Hi Shane,
Welcome to our online FFing community. Glad to have you.
Usually when folks move to PA, their work contraints tend to have them settle in areas with higher population or suburbs. As you'd imagine, these areas often have fewer fishing opportunities, especially for trout. Moreover, people outside of PA tend to see our state through a trout fishing lens. Nothing wrong with that, after all, we're famous mostly for our historical trout fishing legacy. However, warm water fishing opportunities are excellent too and shouldn't be overlooked, especially in western PA, or during warm, hot summers such as this one that can really put the hurt on trout fishing.
Broadly speaking, fishing opportunities, especially for wild trout, are strongest across the central part of the state in the Appalachian range. Big woods counties in the northcentral (eg. Potter, Lycoming, etc.) are paradise for outdoorsmen but, the downside of course, is that job opportunities are fewer. Middle Appalachain counties, such as Centre and Cumberland, have stronger economic profiles and also limestone spring creeks.
I live in the southcentral and am very happy where I'm at. I suppose if I could live anywhere in the state and there were no other factors involved, those northcentral counties would be mighty nice to live in.
Anyway, as you plan your move to PA, stick around our site. Read through the fishing reports (they're by county) and you'll get a feel for fishing opportunities in the different areas of the state.